Charge-transfer complexes of 4-(dimethylamino)pyridine with 2,4-,3,4-and 3,5-dinitrobenzoic acid

Hiroyuki Hosomi, Shigeru Ohba, Yoshikatsu Ito

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6 Citations (Scopus)

Abstract

A study was conducted to investigate charge-transfer complexes of 4-(dimethylamino)pyridine with 2,4-,3,4-and 3,5-dinitrobenzoic acid. It was found that the ions were connected by an N-H?O hydrogen bond in the crystal structures of 4-(dimethylamino)-pyridinium 2,4-dinitrobenzoate, 4-(dimethylamino)pyridinium 3,4-dinitrobenzoate, and 4-(dimethylamino)-pyridinium 3,5-dinitrobenzoate. Equimolecular mixtures of 4-(dimethylamino)pyridine and 2,4-, 3,4- or 3,5-dinitrobenzoic acid were recrystallized from acetone to prepare 4-(dimethylamino)-pyridinium 2,4-dinitrobenzoate, 4-(dimethylamino)pyridinium 3,4-dinitrobenzoate, and 4-(dimethylamino)-pyridinium 3,5-dinitrobenzoate.

Original languageEnglish
Pages (from-to)e149-e150
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number4
DOIs
Publication statusPublished - 2000 Jan 1

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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