Chemical conversion and liquid-liquid extraction of 5-hydroxymethylfurfural from fructose by slug flow microreactor

Toshinori Shimanouchi; Yoshitaka Kataoka; Tatsuya Tanifuji; Yukitaka Kimura; Satoko Fujioka; Koichi Terasaka

doi:10.1002/aic.15201

Chemical conversion and liquid-liquid extraction of 5-hydroxymethylfurfural from fructose by slug flow microreactor

Toshinori Shimanouchi, Yoshitaka Kataoka, Tatsuya Tanifuji, Yukitaka Kimura, Satoko Fujioka, Koichi Terasaka

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

A dehydration of fructose in the water/methyl isobuthyl ketone (MIBK) biphasic system can yield 5-hydroxymethylfurfural (HMF) to be successfully extracted into the organic MIBK phase. The HMF production and yield in MIBK phase was discussed by using a simplified model taking into consideration of the slug flow. The extraction resistance of HMF across the interface between water and MIBK depended on the line velocity and the flow rate ratio. It was likely that the velocity field generated in the slug flow contributed to an increase in the mass transfer of HMF.

Original language	English
Journal	AICHE Journal
DOIs	https://doi.org/10.1002/aic.15201
Publication status	Accepted/In press - 2016

Keywords

Bioprocess engineering
Extraction
Multi-phase flow
Reaction kinetics

ASJC Scopus subject areas

Chemical Engineering(all)
Biotechnology
Environmental Engineering

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10.1002/aic.15201

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title = "Chemical conversion and liquid-liquid extraction of 5-hydroxymethylfurfural from fructose by slug flow microreactor",

abstract = "A dehydration of fructose in the water/methyl isobuthyl ketone (MIBK) biphasic system can yield 5-hydroxymethylfurfural (HMF) to be successfully extracted into the organic MIBK phase. The HMF production and yield in MIBK phase was discussed by using a simplified model taking into consideration of the slug flow. The extraction resistance of HMF across the interface between water and MIBK depended on the line velocity and the flow rate ratio. It was likely that the velocity field generated in the slug flow contributed to an increase in the mass transfer of HMF.",

keywords = "Bioprocess engineering, Extraction, Multi-phase flow, Reaction kinetics",

author = "Toshinori Shimanouchi and Yoshitaka Kataoka and Tatsuya Tanifuji and Yukitaka Kimura and Satoko Fujioka and Koichi Terasaka",

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T1 - Chemical conversion and liquid-liquid extraction of 5-hydroxymethylfurfural from fructose by slug flow microreactor

AU - Shimanouchi, Toshinori

AU - Kataoka, Yoshitaka

AU - Tanifuji, Tatsuya

AU - Kimura, Yukitaka

AU - Fujioka, Satoko

AU - Terasaka, Koichi

PY - 2016

Y1 - 2016

N2 - A dehydration of fructose in the water/methyl isobuthyl ketone (MIBK) biphasic system can yield 5-hydroxymethylfurfural (HMF) to be successfully extracted into the organic MIBK phase. The HMF production and yield in MIBK phase was discussed by using a simplified model taking into consideration of the slug flow. The extraction resistance of HMF across the interface between water and MIBK depended on the line velocity and the flow rate ratio. It was likely that the velocity field generated in the slug flow contributed to an increase in the mass transfer of HMF.

AB - A dehydration of fructose in the water/methyl isobuthyl ketone (MIBK) biphasic system can yield 5-hydroxymethylfurfural (HMF) to be successfully extracted into the organic MIBK phase. The HMF production and yield in MIBK phase was discussed by using a simplified model taking into consideration of the slug flow. The extraction resistance of HMF across the interface between water and MIBK depended on the line velocity and the flow rate ratio. It was likely that the velocity field generated in the slug flow contributed to an increase in the mass transfer of HMF.

KW - Bioprocess engineering

KW - Extraction

KW - Multi-phase flow

KW - Reaction kinetics

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DO - 10.1002/aic.15201

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JO - AICHE Journal

JF - AICHE Journal

ER -

Chemical conversion and liquid-liquid extraction of 5-hydroxymethylfurfural from fructose by slug flow microreactor

Abstract

Keywords

ASJC Scopus subject areas

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