Chemoselective glycosylations using 2,3-unsaturated-4-keto glycosyl donors

Shunichi Kusumi, Sainan Wang, Tatsuya Watanabe, Kaname Sasaki, Daisuke Takahashi, Kazunobu Toshima

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

2,3-Unsaturated-4-keto glycosyl acetates were found to exhibit low reactivity under several glycosylation conditions. Chemoselective glycosylations were effectively performed using 2,3-unsaturated glycosyl and 2,3-dideoxy glycosyl acetates as armed glycosyl donors, and 2,3-unsaturated-4-keto glycosyl acetates as disarmed glycosyl donors.

Original languageEnglish
Pages (from-to)988-990
Number of pages3
JournalOrganic and Biomolecular Chemistry
Volume8
Issue number5
DOIs
Publication statusPublished - 2010

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Glycosylation
acetates
Acetates
reactivity

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

Chemoselective glycosylations using 2,3-unsaturated-4-keto glycosyl donors. / Kusumi, Shunichi; Wang, Sainan; Watanabe, Tatsuya; Sasaki, Kaname; Takahashi, Daisuke; Toshima, Kazunobu.

In: Organic and Biomolecular Chemistry, Vol. 8, No. 5, 2010, p. 988-990.

Research output: Contribution to journalArticle

Kusumi, Shunichi ; Wang, Sainan ; Watanabe, Tatsuya ; Sasaki, Kaname ; Takahashi, Daisuke ; Toshima, Kazunobu. / Chemoselective glycosylations using 2,3-unsaturated-4-keto glycosyl donors. In: Organic and Biomolecular Chemistry. 2010 ; Vol. 8, No. 5. pp. 988-990.
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