Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2: 3,6:7- dibutanocorrphycenato-κ4N)iron(III)

Yoshiki Ohgo, Yuki Yokoyama, Saburo Neya, Mikio Nakamura

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title complex, [Fe(C36H36N4O 4)Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe III atom from the mean pyrrole N4 plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent molecules.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number12
DOIs
Publication statusPublished - 2011 Dec

Fingerprint

Pyrroles
pyrroles
Iron
iron
Atoms
Molecules
atoms
molecules
ferryl iron

Keywords

  • data-to-parameter ratio = 16.1
  • disorder in main residue
  • mean σ(C-C) = 0.011 Å
  • R factor = 0.097
  • single-crystal X-ray study
  • T = 293 K
  • wR factor = 0.305

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2 : 3,6:7- dibutanocorrphycenato-κ4N)iron(III). / Ohgo, Yoshiki; Yokoyama, Yuki; Neya, Saburo; Nakamura, Mikio.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 12, 12.2011.

Research output: Contribution to journalArticle

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AB - The title complex, [Fe(C36H36N4O 4)Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe III atom from the mean pyrrole N4 plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent molecules.

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KW - T = 293 K

KW - wR factor = 0.305

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