Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7- dibutanocorrphycenato-κ4N)iron(III)

Yoshiki Ohgo; Yuki Yokoyama; Saburo Neya; Mikio Nakamura

doi:10.1107/S1600536811051130

Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7- dibutanocorrphycenato-κ⁴N)iron(III)

Yoshiki Ohgo, Yuki Yokoyama, Saburo Neya, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title complex, [Fe(C₃₆H₃₆N₄O ₄)Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe ^III atom from the mean pyrrole N₄ plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent molecules.

Original language	English
Pages (from-to)	m1903-m1904
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811051130
Publication status	Published - 2011 Dec
Externally published	Yes

Keywords

R factor = 0.097
T = 293 K
data-to-parameter ratio = 16.1
disorder in main residue
mean σ(C-C) = 0.011 Å
single-crystal X-ray study
wR factor = 0.305

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536811051130

Cite this

@article{c04f62f14bac4b4999cb2c5692b85ead,

title = "Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7- dibutanocorrphycenato-κ4N)iron(III)",

abstract = "The title complex, [Fe(C36H36N4O 4)Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe III atom from the mean pyrrole N4 plane are 0.418 (3) and 0.465 (3) {\AA} for the two crystallographically independent molecules.",

keywords = "R factor = 0.097, T = 293 K, data-to-parameter ratio = 16.1, disorder in main residue, mean σ(C-C) = 0.011 {\AA}, single-crystal X-ray study, wR factor = 0.305",

author = "Yoshiki Ohgo and Yuki Yokoyama and Saburo Neya and Mikio Nakamura",

year = "2011",

month = dec,

doi = "10.1107/S1600536811051130",

language = "English",

volume = "67",

pages = "m1903--m1904",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7- dibutanocorrphycenato-κ4N)iron(III)

AU - Ohgo, Yoshiki

AU - Yokoyama, Yuki

AU - Neya, Saburo

AU - Nakamura, Mikio

PY - 2011/12

Y1 - 2011/12

N2 - The title complex, [Fe(C36H36N4O 4)Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe III atom from the mean pyrrole N4 plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent molecules.

AB - The title complex, [Fe(C36H36N4O 4)Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe III atom from the mean pyrrole N4 plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent molecules.

KW - R factor = 0.097

KW - T = 293 K

KW - data-to-parameter ratio = 16.1

KW - disorder in main residue

KW - mean σ(C-C) = 0.011 Å

KW - single-crystal X-ray study

KW - wR factor = 0.305

UR - http://www.scopus.com/inward/record.url?scp=83155185584&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=83155185584&partnerID=8YFLogxK

U2 - 10.1107/S1600536811051130

DO - 10.1107/S1600536811051130

M3 - Article

C2 - 22199660

AN - SCOPUS:83155185584

SN - 1600-5368

VL - 67

SP - m1903-m1904

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -