Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate

Y. Ohgo; S. Neya; T. Ikeue; N. Funasaki; M. Nakamura

doi:10.1107/S0108270101009842

Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ⁴N)iron(III) chloroform solvate

Y. Ohgo, S. Neya, T. Ikeue, N. Funasaki, M. Nakamura

Department of Applied Chemistry

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.1^2,5.1^8,11.1^12,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C₃₃H₃₇N₄)Cl]·CHCl₃, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central Fe^III atom from the least-squares plane of the C₂₀N₄ core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

Original language	English
Pages (from-to)	1046-1047
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	9
DOIs	https://doi.org/10.1107/S0108270101009842
Publication status	Published - 2001 Sep

ASJC Scopus subject areas

Condensed Matter Physics
Structural Biology

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Ohgo, Y., Neya, S., Ikeue, T., Funasaki, N., & Nakamura, M. (2001). Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ⁴N)iron(III) chloroform solvate. Acta Crystallographica Section C: Crystal Structure Communications, 57(9), 1046-1047. https://doi.org/10.1107/S0108270101009842

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title = "Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate",

abstract = "The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) {\AA}. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) {\AA}; Fe-Cl 2.232 (1) {\AA}.",

author = "Y. Ohgo and S. Neya and T. Ikeue and N. Funasaki and M. Nakamura",

year = "2001",

month = sep,

doi = "10.1107/S0108270101009842",

language = "English",

volume = "57",

pages = "1046--1047",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate

AU - Ohgo, Y.

AU - Neya, S.

AU - Ikeue, T.

AU - Funasaki, N.

AU - Nakamura, M.

PY - 2001/9

Y1 - 2001/9

N2 - The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

AB - The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

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JO - Acta Crystallographica Section C: Crystal Structure Communications

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