Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate

Y. Ohgo, S. Neya, T. Ikeue, N. Funasaki, M. Nakamura

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

Original languageEnglish
Pages (from-to)1046-1047
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume57
Issue number9
DOIs
Publication statusPublished - 2001 Sep

Fingerprint

Chloroform
Least-Squares Analysis
chloroform
Iron
X-Rays
iron
X rays
Atoms
deviation
atoms
x rays

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate. / Ohgo, Y.; Neya, S.; Ikeue, T.; Funasaki, N.; Nakamura, M.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 57, No. 9, 09.2001, p. 1046-1047.

Research output: Contribution to journalArticle

Ohgo, Y. ; Neya, S. ; Ikeue, T. ; Funasaki, N. ; Nakamura, M. / Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate. In: Acta Crystallographica Section C: Crystal Structure Communications. 2001 ; Vol. 57, No. 9. pp. 1046-1047.
@article{0def5faaef014f269944f9a4ad5d0f3d,
title = "Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate",
abstract = "The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) {\AA}. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) {\AA}; Fe-Cl 2.232 (1) {\AA}.",
author = "Y. Ohgo and S. Neya and T. Ikeue and N. Funasaki and M. Nakamura",
year = "2001",
month = "9",
doi = "10.1107/S0108270101009842",
language = "English",
volume = "57",
pages = "1046--1047",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "9",

}

TY - JOUR

T1 - Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate

AU - Ohgo, Y.

AU - Neya, S.

AU - Ikeue, T.

AU - Funasaki, N.

AU - Nakamura, M.

PY - 2001/9

Y1 - 2001/9

N2 - The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

AB - The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

UR - http://www.scopus.com/inward/record.url?scp=0035437827&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035437827&partnerID=8YFLogxK

U2 - 10.1107/S0108270101009842

DO - 10.1107/S0108270101009842

M3 - Article

C2 - 11588366

AN - SCOPUS:0035437827

VL - 57

SP - 1046

EP - 1047

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 9

ER -