TY - JOUR
T1 - Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate
AU - Ohgo, Y.
AU - Neya, S.
AU - Ikeue, T.
AU - Funasaki, N.
AU - Nakamura, M.
PY - 2001/9
Y1 - 2001/9
N2 - The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.
AB - The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [16.2.1.12,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.
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U2 - 10.1107/S0108270101009842
DO - 10.1107/S0108270101009842
M3 - Article
C2 - 11588366
AN - SCOPUS:0035437827
VL - 57
SP - 1046
EP - 1047
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 9
ER -