In the chloroiron(III) complex of meso-tetrapropylporphyrin, [Fe(C32H36N4)Cl], the FeIII atom has slightly distorted square-pyramidal coordination. The porphyrin ring shows a typical S4-ruffled structure in addition to a normally observed domed core; the deviations of the meso-C and Fe atoms from the least-squares plane of the C20N4 core are 0.366(4) (maximum) and 0.578(1) Å, respectively. The average Fe - Np bond distance is 2.063 (4) Å.
|Number of pages||3|
|Journal||Acta Crystallographica Section C: Crystal Structure Communications|
|Publication status||Published - 1999 Nov 15|
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)