Abstract
Induced circular dichroism (ICD) was observed in binaphthyl amides of chiral primary amines. The CDs changed to split curves centered at 225 nm after N-methylation. The calculated screw senses of the two naphthyl groups accorded with those expected from their exciton chiralities, indicating a possible application for determination of absolute configuration.
| Original language | English |
|---|---|
| Pages (from-to) | 58-61 |
| Number of pages | 4 |
| Journal | Letters in Organic Chemistry |
| Volume | 3 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2006 Jan |
Keywords
- Amide
- Binaphthyl
- Cotton effect
- Exciton chirality
- Induced circular dichroism
- Screw sense
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
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Cite this
Hosoi, S., Serata, J., Sakushima, A., Kiuchi, F., Takahashi, I., & Ohta, T. (2006). Circular dichroism in a chiral amide possessing an achiral binaphthyl chromophore. Letters in Organic Chemistry, 3(1), 58-61. https://doi.org/10.2174/157017806774964404