Cobalt-carbene complex with single-bond character: Intermediate for the cobalt complex-catalyzed cyclopropanation

Taketo Ikeno, Izumi Iwakura, Tohru Yamada

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

It is generally considered that metal-carbene carbon bonds in carbene complexes for cyclopropanation should be double-bonded; however, the theoretical and FT-IR analyses revealed that the cobalt-carbene carbon bond of the 3-oxobutylideneaminato or the salen-cobalt-carbene complexes was characterized as a single bond.

Original languageEnglish
Pages (from-to)15152-15153
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number51
DOIs
Publication statusPublished - 2002 Dec 25

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Cobalt
Carbon
Metals
single bond
carbene

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  • Chemistry(all)

Cite this

Cobalt-carbene complex with single-bond character : Intermediate for the cobalt complex-catalyzed cyclopropanation. / Ikeno, Taketo; Iwakura, Izumi; Yamada, Tohru.

In: Journal of the American Chemical Society, Vol. 124, No. 51, 25.12.2002, p. 15152-15153.

Research output: Contribution to journalArticle

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