Cobalt-catalyzed reductive carboxylation of α,β-unsaturated compounds with carbon dioxide

Chika Hayashi, Takuo Hayashi, Tohru Yamada

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The gaseous carbon dioxide incorporation reaction with α,β-unsaturated compounds was examined in the presence of a catalytic amount of bis(acetylacetonato)cobalt(II) and using diethylzinc as a reductant. After screening with various electron-withdrawing groups, both α,β-unsaturated nitriles and carboxamides were found to efficiently capture carbon dioxide to provide the corresponding carboxylates or malonates in good to excellent yields under mild conditions.

Original languageEnglish
Pages (from-to)862-870
Number of pages9
JournalBulletin of the Chemical Society of Japan
Volume88
Issue number6
DOIs
Publication statusPublished - 2015

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Unsaturated compounds
Carboxylation
Cobalt
Carbon Dioxide
Malonates
Nitriles
Reducing Agents
Screening
Electrons

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Cobalt-catalyzed reductive carboxylation of α,β-unsaturated compounds with carbon dioxide. / Hayashi, Chika; Hayashi, Takuo; Yamada, Tohru.

In: Bulletin of the Chemical Society of Japan, Vol. 88, No. 6, 2015, p. 862-870.

Research output: Contribution to journalArticle

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