Columnar/herringbone dual crystal packing of pyrenylsumanene and its photophysical properties

Binod Babu Shrestha; Shuhei Higashibayashi; Hidehiro Sakurai

doi:10.3762/bjoc.10.80

Columnar/herringbone dual crystal packing of pyrenylsumanene and its photophysical properties

Binod Babu Shrestha, Shuhei Higashibayashi, Hidehiro Sakurai

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A single crystal of pyrenylsumanene was found to exhibit both columnar and herringbone crystal packing. The sumanene moieties form unidirectional columnar structures based on ππ stacking while the pyrene moieties generate herringbone structures due to CHπ interactions. The absorption and emission maxima of pyrenylsumanene were both red-shifted relative to those of sumanene and pyrene, owing to the extension of π-conjugation. Monomer emission with high quantum yield (0.82) was observed for pyrenylsumanene in solution, while excimer-type red-shifted emission was evident in the crystalline phase.

Original language	English
Pages (from-to)	841-847
Number of pages	7
Journal	Beilstein Journal of Organic Chemistry
Volume	10
DOIs	https://doi.org/10.3762/bjoc.10.80
Publication status	Published - 2014 Apr 11
Externally published	Yes

Keywords

Carbon nanomaterials
Columnar crystal packing
Fluorescence
Herringbone
Pyrenylsumanene

ASJC Scopus subject areas

Organic Chemistry

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10.3762/bjoc.10.80

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abstract = "A single crystal of pyrenylsumanene was found to exhibit both columnar and herringbone crystal packing. The sumanene moieties form unidirectional columnar structures based on ππ stacking while the pyrene moieties generate herringbone structures due to CHπ interactions. The absorption and emission maxima of pyrenylsumanene were both red-shifted relative to those of sumanene and pyrene, owing to the extension of π-conjugation. Monomer emission with high quantum yield (0.82) was observed for pyrenylsumanene in solution, while excimer-type red-shifted emission was evident in the crystalline phase.",

keywords = "Carbon nanomaterials, Columnar crystal packing, Fluorescence, Herringbone, Pyrenylsumanene",

author = "Shrestha, {Binod Babu} and Shuhei Higashibayashi and Hidehiro Sakurai",

year = "2014",

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doi = "10.3762/bjoc.10.80",

language = "English",

volume = "10",

pages = "841--847",

journal = "Beilstein Journal of Organic Chemistry",

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T1 - Columnar/herringbone dual crystal packing of pyrenylsumanene and its photophysical properties

AU - Shrestha, Binod Babu

AU - Higashibayashi, Shuhei

AU - Sakurai, Hidehiro

PY - 2014/4/11

Y1 - 2014/4/11

N2 - A single crystal of pyrenylsumanene was found to exhibit both columnar and herringbone crystal packing. The sumanene moieties form unidirectional columnar structures based on ππ stacking while the pyrene moieties generate herringbone structures due to CHπ interactions. The absorption and emission maxima of pyrenylsumanene were both red-shifted relative to those of sumanene and pyrene, owing to the extension of π-conjugation. Monomer emission with high quantum yield (0.82) was observed for pyrenylsumanene in solution, while excimer-type red-shifted emission was evident in the crystalline phase.

AB - A single crystal of pyrenylsumanene was found to exhibit both columnar and herringbone crystal packing. The sumanene moieties form unidirectional columnar structures based on ππ stacking while the pyrene moieties generate herringbone structures due to CHπ interactions. The absorption and emission maxima of pyrenylsumanene were both red-shifted relative to those of sumanene and pyrene, owing to the extension of π-conjugation. Monomer emission with high quantum yield (0.82) was observed for pyrenylsumanene in solution, while excimer-type red-shifted emission was evident in the crystalline phase.

KW - Carbon nanomaterials

KW - Columnar crystal packing

KW - Fluorescence

KW - Herringbone

KW - Pyrenylsumanene

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JO - Beilstein Journal of Organic Chemistry

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Columnar/herringbone dual crystal packing of pyrenylsumanene and its photophysical properties

Abstract

Keywords

ASJC Scopus subject areas

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