Compensation for the birefrigence of an optical polymer by the anisotropic molecule dopant method and design of the anisotropic molecule dopant

Hidetoshi Takahashi, Ryo Tanaka, Hisanori Ohkita, Akihiro Tagaya, Yasuhiro Koike

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Birefringence induced by the orientation of polymer main chains during an injection-molding or extrusion processing degrades the performance of optical devices that require maintaining the polarization state of incident light. We have compensated for the birefringence of optical polymers by the anisotropic molecule dopant method. The anisotropic molecule dopant method has problems that thermal degradation and the bleedout of an anisotropic molecule in an injection molding. In this study, we designed biphenyl-3,4,3',4'-tetracarboxylic acid tetramethyl ester (BPTM) as an anisotropic molecule for an application to an injection molding. The birefringence of the injection molded poly(methylmethacrylate)(PMMA) samples doped with 7 wt% of BPTM was reduced by about 90% compared to the PMMA sample.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages3869-3870
Number of pages2
Volume55
Edition2
Publication statusPublished - 2006
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

Fingerprint

Birefringence
Doping (additives)
Injection molding
Molecules
Polymers
Optical devices
Extrusion
Esters
Pyrolysis
Polarization
Acids
Compensation and Redress
Processing

Keywords

  • Anisotropic molecule dopant method
  • Birefringence
  • Injection molding
  • Poly(methyl methacrylate)

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Compensation for the birefrigence of an optical polymer by the anisotropic molecule dopant method and design of the anisotropic molecule dopant. / Takahashi, Hidetoshi; Tanaka, Ryo; Ohkita, Hisanori; Tagaya, Akihiro; Koike, Yasuhiro.

Polymer Preprints, Japan. Vol. 55 2. ed. 2006. p. 3869-3870.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Takahashi, H, Tanaka, R, Ohkita, H, Tagaya, A & Koike, Y 2006, Compensation for the birefrigence of an optical polymer by the anisotropic molecule dopant method and design of the anisotropic molecule dopant. in Polymer Preprints, Japan. 2 edn, vol. 55, pp. 3869-3870, 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan, 06/9/20.
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