Comprehensive refractive index property for room-temperature ionic liquids

Shiro Seki, Seiji Tsuzuki, Kikuko Hayamizu, Yasuhiro Umebayashi, Nobuyuki Serizawa, Katsuhito Takei, Hajime Miyashiro

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116 Citations (Scopus)

Abstract

Refractive index, an optical property, and liquid density were measured for 17 types of room-temperature ionic liquids at various temperatures. Ab initio calculations were performed to yield theoretical polarizability of the respective ionic liquid composing ions. A highly linear correlation was found between the experimental refractive index and the predicted polarizability normalized in terms of the molar volume. This suggests that the electronic polarization of the ionic liquid composing ions predominantly contributes to the refractive index of the room-temperature ionic liquids.

Original languageEnglish
Pages (from-to)2211-2216
Number of pages6
JournalJournal of Chemical and Engineering Data
Volume57
Issue number8
DOIs
Publication statusPublished - 2012 Aug 9
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Seki, S., Tsuzuki, S., Hayamizu, K., Umebayashi, Y., Serizawa, N., Takei, K., & Miyashiro, H. (2012). Comprehensive refractive index property for room-temperature ionic liquids. Journal of Chemical and Engineering Data, 57(8), 2211-2216. https://doi.org/10.1021/je201289w