Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

Akira Ikezaki, Hideyuki Tukada, Mikio Nakamura

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

Original languageEnglish
Pages (from-to)2257-2259
Number of pages3
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - 2008
Externally publishedYes

Fingerprint

Thymidine Monophosphate
Porphyrins
Ground state
Electronic structure
Iron
Positive ions
Ligands
Cations
imidazole

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands. / Ikezaki, Akira; Tukada, Hideyuki; Nakamura, Mikio.

In: Chemical Communications, No. 19, 2008, p. 2257-2259.

Research output: Contribution to journalArticle

Ikezaki, Akira ; Tukada, Hideyuki ; Nakamura, Mikio. / Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands. In: Chemical Communications. 2008 ; No. 19. pp. 2257-2259.
@article{1cc07e938dad475e80d1e376414a31f9,
title = "Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands",
abstract = "Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.",
author = "Akira Ikezaki and Hideyuki Tukada and Mikio Nakamura",
year = "2008",
doi = "10.1039/b800674a",
language = "English",
pages = "2257--2259",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "19",

}

TY - JOUR

T1 - Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

AU - Ikezaki, Akira

AU - Tukada, Hideyuki

AU - Nakamura, Mikio

PY - 2008

Y1 - 2008

N2 - Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

AB - Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

UR - http://www.scopus.com/inward/record.url?scp=46749136386&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=46749136386&partnerID=8YFLogxK

U2 - 10.1039/b800674a

DO - 10.1039/b800674a

M3 - Article

AN - SCOPUS:46749136386

SP - 2257

EP - 2259

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 19

ER -