Abstract
Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.
| Original language | English |
|---|---|
| Pages (from-to) | 350-354 |
| Number of pages | 5 |
| Journal | Carbon |
| Volume | 130 |
| DOIs | |
| Publication status | Published - 2018 Apr 1 |
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ASJC Scopus subject areas
- Chemistry(all)
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Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK). / Yamamoto, Takashi; Akahori, Miku; Natsui, Keisuke; Saitoh, Tsuyoshi; Einaga, Yasuaki.
In: Carbon, Vol. 130, 01.04.2018, p. 350-354.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)
AU - Yamamoto, Takashi
AU - Akahori, Miku
AU - Natsui, Keisuke
AU - Saitoh, Tsuyoshi
AU - Einaga, Yasuaki
PY - 2018/4/1
Y1 - 2018/4/1
N2 - Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.
AB - Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.
UR - http://www.scopus.com/inward/record.url?scp=85040373746&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85040373746&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2017.12.098
DO - 10.1016/j.carbon.2017.12.098
M3 - Article
VL - 130
SP - 350
EP - 354
JO - Carbon
JF - Carbon
SN - 0008-6223
ER -