Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)

Takashi Yamamoto, Miku Akahori, Keisuke Natsui, Tsuyoshi Saitoh, Yasuaki Einaga

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.

Original languageEnglish
Pages (from-to)350-354
Number of pages5
JournalCarbon
Volume130
DOIs
Publication statusPublished - 2018 Apr 1

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Diamond
Boron
Copper
Diamonds
Alkynes
Azides
Electrodes
Molecular electronics
Molecular recognition
Catalysts
Cycloaddition
Biological systems
Chemical analysis

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK). / Yamamoto, Takashi; Akahori, Miku; Natsui, Keisuke; Saitoh, Tsuyoshi; Einaga, Yasuaki.

In: Carbon, Vol. 130, 01.04.2018, p. 350-354.

Research output: Contribution to journalArticle

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