Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)

Takashi Yamamoto; Miku Akahori; Keisuke Natsui; Tsuyoshi Saitoh; Yasuaki Einaga

doi:10.1016/j.carbon.2017.12.098

Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)

Takashi Yamamoto, Miku Akahori, Keisuke Natsui, Tsuyoshi Saitoh, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.

Original language	English
Pages (from-to)	350-354
Number of pages	5
Journal	Carbon
Volume	130
DOIs	https://doi.org/10.1016/j.carbon.2017.12.098
Publication status	Published - 2018 Apr

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)

Access to Document

10.1016/j.carbon.2017.12.098

Cite this

@article{9909734315af44b29e2a187b9a7d7f50,

title = "Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)",

abstract = "Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.",

author = "Takashi Yamamoto and Miku Akahori and Keisuke Natsui and Tsuyoshi Saitoh and Yasuaki Einaga",

year = "2018",

month = apr,

doi = "10.1016/j.carbon.2017.12.098",

language = "English",

volume = "130",

pages = "350--354",

journal = "Carbon",

issn = "0008-6223",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)

AU - Yamamoto, Takashi

AU - Akahori, Miku

AU - Natsui, Keisuke

AU - Saitoh, Tsuyoshi

AU - Einaga, Yasuaki

PY - 2018/4

Y1 - 2018/4

N2 - Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.

AB - Controlled surface functionalization of electrode materials is an important technique in various fields such as analytical chemistry, molecular electronics, and molecular recognition in biological systems. In this work, we report the control decoration of boron-doped diamond (BDD) electrodes by electrochemically driven copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of alkyne and azide (e−CLICK) in which the catalyst is produced by electroreduction of copper(II) species. As the e−CLICK strategy enabled to tune the produced amount of the copper(I) catalyst electrochemically, the alkyne-terminated BDD electrodes were decorated with azide-terminated ferrocene in a controlled manner.

UR - http://www.scopus.com/inward/record.url?scp=85040373746&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85040373746&partnerID=8YFLogxK

U2 - 10.1016/j.carbon.2017.12.098

DO - 10.1016/j.carbon.2017.12.098

M3 - Article

AN - SCOPUS:85040373746

VL - 130

SP - 350

EP - 354

JO - Carbon

JF - Carbon

SN - 0008-6223

ER -

Controlled decoration of boron-doped diamond electrodes by electrochemical click reaction (e−CLICK)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this