Controlled Orientations of Neighboring Tetracene Units by Mixed Self-Assembled Monolayers on Gold Nanoclusters for High-Yield and Long-Lived Triplet Excited States through Singlet Fission

Toshiyuki Saegusa, Hayato Sakai, Hiroki Nagashima, Yasuhiro Kobori, Nikolai V. Tkachenko, Taku Hasobe

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Although tetracene (Tc) is well-known as a good candidate for singlet fission (SF), the number of high-yield and long-lived triplet excited states through SF is extremely limited because of the relative acceleration of the reverse triplet-triplet annihilation (TTA) considering the energy matching between a singlet and two triplet states. Systematic control of electronic interactions between two neighboring units using conventional covalent linkages and molecular assembly methods to optimize these kinetic processes is quite difficult because of the complicated synthesis and random orientations. In this study, we propose a novel supramolecular strategy utilizing mixed self-assembled monolayers (SAMs) with two different chain lengths. Specifically, mixed Tc-SAMs on gold nanoclusters, which are prepared using Tc-modified heterodisulfides with two different chain lengths, attain high-yield SF (ΦSF ≈ 90%) and individual triplet yields (ΦΤ ≈ 160%). The obtained ΦSF is the highest value among Tc derivatives in homogeneous solution to the best of our knowledge.

Original languageEnglish
Pages (from-to)14720-14727
Number of pages8
JournalJournal of the American Chemical Society
Volume141
Issue number37
DOIs
Publication statusPublished - 2019 Sep 18

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Nanoclusters
Self assembled monolayers
Chain length
Excited states
Gold
Derivatives
Kinetics
naphthacene

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Controlled Orientations of Neighboring Tetracene Units by Mixed Self-Assembled Monolayers on Gold Nanoclusters for High-Yield and Long-Lived Triplet Excited States through Singlet Fission. / Saegusa, Toshiyuki; Sakai, Hayato; Nagashima, Hiroki; Kobori, Yasuhiro; Tkachenko, Nikolai V.; Hasobe, Taku.

In: Journal of the American Chemical Society, Vol. 141, No. 37, 18.09.2019, p. 14720-14727.

Research output: Contribution to journalArticle

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AU - Saegusa, Toshiyuki

AU - Sakai, Hayato

AU - Nagashima, Hiroki

AU - Kobori, Yasuhiro

AU - Tkachenko, Nikolai V.

AU - Hasobe, Taku

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