TY - JOUR
T1 - Controlling open-circuit voltage of organic photovoltaic cells by inserting thin layer of Zn-phthalocyanine at pentacene/C60 interface
AU - Kinoshita, Yoshiki
AU - Hasobe, Taku
AU - Murata, Hideyuki
PY - 2008/2/15
Y1 - 2008/2/15
N2 - We demonstrate organic photovoltaic cells composed of multi charge-separation (MCS) interfaces in the active layer for the improvement of power conversion efficiency (ηp). The MCS interfaces are composed of pentacene/C60 and Zn-phthalocyanine (ZnPc)/C60 by inserting thin layer of ZnPc at the CS interface between pentacene/C 60. We obtain enhanced ηp and Voc in accordance with the increased energy difference between the lowest unoccupied molecular orbital (LUMO) level of the n-type material (C60) and the HOMO level of the p-type material (ZnPc). By inserting 2nm ZnPc at the interface, both open-circuit voltage (Voc) and short-circuit current density (Jsc) have been improved simultaneously and the resulting ηp reaches 2.07%.
AB - We demonstrate organic photovoltaic cells composed of multi charge-separation (MCS) interfaces in the active layer for the improvement of power conversion efficiency (ηp). The MCS interfaces are composed of pentacene/C60 and Zn-phthalocyanine (ZnPc)/C60 by inserting thin layer of ZnPc at the CS interface between pentacene/C 60. We obtain enhanced ηp and Voc in accordance with the increased energy difference between the lowest unoccupied molecular orbital (LUMO) level of the n-type material (C60) and the HOMO level of the p-type material (ZnPc). By inserting 2nm ZnPc at the interface, both open-circuit voltage (Voc) and short-circuit current density (Jsc) have been improved simultaneously and the resulting ηp reaches 2.07%.
KW - Multi charge separation (MCS) interfaces
KW - V and J controlled independently
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U2 - 10.1143/JJAP.47.1234
DO - 10.1143/JJAP.47.1234
M3 - Article
AN - SCOPUS:54249142193
VL - 47
SP - 1234
EP - 1237
JO - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes
JF - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes
SN - 0021-4922
IS - 2 PART 2
ER -