Ethanol molecules were irradiated with a pair of temporally overlapping ultrashort intense laser pulses (1013 - 1014 W cm2) with different colors of 400 and 800 nm, and the dissociative ionization processes have been investigated. The yield ratio of the C-O bond breaking with respect to the C-C bond breaking was varied in the range of 0.17-0.53 sensitively depending on the delay time between the two laser pulses, and the absolute value of the yield of the C-O bond breaking was found to be increased largely when the Fourier-transform limited 800 nm laser pulse overlaps the stretched 400 nm laser pulse, demonstrating an advantage of the two-color intense laser fields in controlling chemical bond breaking processes.
|Journal||Journal of Chemical Physics|
|Publication status||Published - 2007|
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry