Convergent Synthesis of Digalactosyl Diacylglycerols

Shinsuke Inuki, Junichiro Kishi, Emi Kashiwabara, Toshihiko Aiba, Yukari Fujimoto

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Efficient convergent chemical syntheses of digalactosyl diacylglycerols (DGDGs), which have both a galactose-galactose α(1→6)-linkage and a galactose-glycerol β-linkage along with a diacylglycerol containing various kinds of fatty acids, have been accomplished. In order to achieve a concise synthesis, we chose to use allylic protective groups as permanent protective groups. We have also achieved α- and β-selective glycosylations for the respective linkages with high yields as the key steps.

Original languageEnglish
Pages (from-to)6482-6485
Number of pages4
JournalOrganic Letters
Volume19
Issue number24
DOIs
Publication statusPublished - 2017 Dec 15

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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