Coordination structure and magnetic property of poly(pyridilenemethylidenenitriloiron)s

Hiroyuki Nishide; Naoki Yoshioka; Eishun Tsuchida; Hidenari Inoue

doi:10.1002/pola.1989.080270210

Coordination structure and magnetic property of poly(pyridilenemethylidenenitriloiron)s

Hiroyuki Nishide, Naoki Yoshioka, Eishun Tsuchida, Hidenari Inoue

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Poly[bis(2,6‐pyridinediylmethylidenenitrilohexamethylenenitrilomethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mössbauer spectroscopy and x‐ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.

Original language	English
Pages (from-to)	497-505
Number of pages	9
Journal	Journal of Polymer Science Part A: Polymer Chemistry
Volume	27
Issue number	2
DOIs	https://doi.org/10.1002/pola.1989.080270210
Publication status	Published - 1989 Jan 30
Externally published	Yes

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pola.1989.080270210

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abstract = "Poly[bis(2,6‐pyridinediylmethylidenenitrilohexamethylenenitrilomethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. M{\"o}ssbauer spectroscopy and x‐ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.",

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AU - Nishide, Hiroyuki

AU - Yoshioka, Naoki

AU - Tsuchida, Eishun

AU - Inoue, Hidenari

PY - 1989/1/30

Y1 - 1989/1/30

N2 - Poly[bis(2,6‐pyridinediylmethylidenenitrilohexamethylenenitrilomethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mössbauer spectroscopy and x‐ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.

AB - Poly[bis(2,6‐pyridinediylmethylidenenitrilohexamethylenenitrilomethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mössbauer spectroscopy and x‐ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.

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JF - Journal of Polymer Science, Part A: Polymer Chemistry

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Coordination structure and magnetic property of poly(pyridilenemethylidenenitriloiron)s

Abstract

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