Corelationship between local structure and water purifying ability of iron-containing waste glasses

Shiro Kubuki; Norifumi Kawakami; Takamitsu Kamikawa; Masayuki Fukagawa; Toshiharu Nishizumi; Tetsuaki Nishida; Zoltán Homonnay; Erno Kuzmann

doi:10.1007/s10751-006-9304-7

Corelationship between local structure and water purifying ability of iron-containing waste glasses

Shiro Kubuki, Norifumi Kawakami, Takamitsu Kamikawa, Masayuki Fukagawa, Toshiharu Nishizumi, Tetsuaki Nishida, Zoltán Homonnay, Erno Kuzmann

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A relationship between the structure and water purifying ability of waste glass prepared from household garbage and Fe₂O₃ was examined by ⁵⁷Fe-Mössbauer and induced coupled plasma (ICP) measurements. From the Debye temperature of waste glass, Fe^II proved to be loosely bound in the glass network as a network modifier. Dissolution amount of Fe^III into artificial drain can be controlled from 0.14 to 0.35 mg/l by changing the Fe₂O₃ content. It proved that chemical oxygen demand (COD) decreases in proportion to the content of Fe ^III, indicating that iron causes decomposition of organic and phosphorus compounds.

Original language	English
Pages (from-to)	429-436
Number of pages	8
Journal	Hyperfine Interactions
Volume	166
Issue number	1-4
DOIs	https://doi.org/10.1007/s10751-006-9304-7
Publication status	Published - 2005 Nov
Externally published	Yes

Keywords

Chemical oxygen demand (COD)
Debye temperature
Fe-Mössbauer spectra
Iron-containing silicate glass

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Nuclear and High Energy Physics
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1007/s10751-006-9304-7

Cite this

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abstract = "A relationship between the structure and water purifying ability of waste glass prepared from household garbage and Fe2O3 was examined by 57Fe-M{\"o}ssbauer and induced coupled plasma (ICP) measurements. From the Debye temperature of waste glass, FeII proved to be loosely bound in the glass network as a network modifier. Dissolution amount of FeIII into artificial drain can be controlled from 0.14 to 0.35 mg/l by changing the Fe2O3 content. It proved that chemical oxygen demand (COD) decreases in proportion to the content of Fe III, indicating that iron causes decomposition of organic and phosphorus compounds.",

keywords = "Chemical oxygen demand (COD), Debye temperature, Fe-M{\"o}ssbauer spectra, Iron-containing silicate glass",

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doi = "10.1007/s10751-006-9304-7",

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T1 - Corelationship between local structure and water purifying ability of iron-containing waste glasses

AU - Kubuki, Shiro

AU - Kawakami, Norifumi

AU - Kamikawa, Takamitsu

AU - Fukagawa, Masayuki

AU - Nishizumi, Toshiharu

AU - Nishida, Tetsuaki

AU - Homonnay, Zoltán

AU - Kuzmann, Erno

PY - 2005/11

Y1 - 2005/11

N2 - A relationship between the structure and water purifying ability of waste glass prepared from household garbage and Fe2O3 was examined by 57Fe-Mössbauer and induced coupled plasma (ICP) measurements. From the Debye temperature of waste glass, FeII proved to be loosely bound in the glass network as a network modifier. Dissolution amount of FeIII into artificial drain can be controlled from 0.14 to 0.35 mg/l by changing the Fe2O3 content. It proved that chemical oxygen demand (COD) decreases in proportion to the content of Fe III, indicating that iron causes decomposition of organic and phosphorus compounds.

AB - A relationship between the structure and water purifying ability of waste glass prepared from household garbage and Fe2O3 was examined by 57Fe-Mössbauer and induced coupled plasma (ICP) measurements. From the Debye temperature of waste glass, FeII proved to be loosely bound in the glass network as a network modifier. Dissolution amount of FeIII into artificial drain can be controlled from 0.14 to 0.35 mg/l by changing the Fe2O3 content. It proved that chemical oxygen demand (COD) decreases in proportion to the content of Fe III, indicating that iron causes decomposition of organic and phosphorus compounds.

KW - Chemical oxygen demand (COD)

KW - Debye temperature

KW - Fe-Mössbauer spectra

KW - Iron-containing silicate glass

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Corelationship between local structure and water purifying ability of iron-containing waste glasses

Abstract

Keywords

ASJC Scopus subject areas

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