CO2 reduction to formic acid at low overpotential on BDD electrodes modified with nanostructured CeO2

Enrico Verlato, Simona Barison, Yasuaki Einaga, Stefano Fasolin, Marco Musiani, Lucia Nasi, Keisuke Natsui, Francesco Paolucci, Giovanni Valenti

Research output: Contribution to journalArticle

Abstract

Ceria was deposited onto boron doped polycrystalline diamond (BDD) cathodes, through electrochemically induced precipitation from nitrate-based solutions. The deposits were characterized using SEM-EDS, HRTEM, XRD and XPS. The morphology, thickness and composition of ceria films, which besides CeO2 contained Ce(OH)3 when prepared at very negative potential, were controlled by tuning the deposition parameters. Thin Ce(OH)3-free ceria films allowed CO2 electrochemical reduction at overpotentials below 50 mV, yielding formic acid with faradaic yield higher than 40% and stable performance for many hours. Ceria seemed to act as a co-catalyst that activated CO2 for reduction at the H-terminated BDD surface, because comparable results were not obtained with ceria-coated glassy carbon electrodes.

Original languageEnglish
Pages (from-to)17896-17905
Number of pages10
JournalJournal of Materials Chemistry A
Volume7
Issue number30
DOIs
Publication statusPublished - 2019 Jan 1

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formic acid
Diamond
Boron
Formic acid
Cerium compounds
Diamonds
Electrodes
Glassy carbon
Nitrates
Energy dispersive spectroscopy
Cathodes
Deposits
X ray photoelectron spectroscopy
Tuning
Scanning electron microscopy
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

CO2 reduction to formic acid at low overpotential on BDD electrodes modified with nanostructured CeO2. / Verlato, Enrico; Barison, Simona; Einaga, Yasuaki; Fasolin, Stefano; Musiani, Marco; Nasi, Lucia; Natsui, Keisuke; Paolucci, Francesco; Valenti, Giovanni.

In: Journal of Materials Chemistry A, Vol. 7, No. 30, 01.01.2019, p. 17896-17905.

Research output: Contribution to journalArticle

Verlato, E, Barison, S, Einaga, Y, Fasolin, S, Musiani, M, Nasi, L, Natsui, K, Paolucci, F & Valenti, G 2019, 'CO2 reduction to formic acid at low overpotential on BDD electrodes modified with nanostructured CeO2', Journal of Materials Chemistry A, vol. 7, no. 30, pp. 17896-17905. https://doi.org/10.1039/c9ta01000a
Verlato, Enrico ; Barison, Simona ; Einaga, Yasuaki ; Fasolin, Stefano ; Musiani, Marco ; Nasi, Lucia ; Natsui, Keisuke ; Paolucci, Francesco ; Valenti, Giovanni. / CO2 reduction to formic acid at low overpotential on BDD electrodes modified with nanostructured CeO2. In: Journal of Materials Chemistry A. 2019 ; Vol. 7, No. 30. pp. 17896-17905.
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AU - Musiani, Marco

AU - Nasi, Lucia

AU - Natsui, Keisuke

AU - Paolucci, Francesco

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