Cr-Triggered Local Structural Change in Cr2Ge2Te6 Phase Change Material

Shogo Hatayama, Yi Shuang, Paul Fons, Yuta Saito, Alexander V. Kolobov, Keisuke Kobayashi, Satoshi Shindo, Daisuke Ando, Yuji Sutou

Research output: Contribution to journalArticle

Abstract

Cr2Ge2Te6 (CrGT) is a phase change material with higher resistivity in the crystalline phase than in the amorphous phase. CrGT exhibits an ultralow operation energy for amorphization. In this study, the origin of the increased resistance in crystalline CrGT compared to amorphous CrGT and the underlying phase change mechanism were investigated in terms of both local structural change and associated change in electronic state. The density of states at the Fermi level in crystalline CrGT decreased with increasing annealing temperature and became negligible upon annealing at 380 °C. Simultaneously, the Fermi level shifted from the vicinity of the valence band to the band gap center, leading to an increase in resistance. The phase change from amorphous to crystalline CrGT occurred through a metastable crystalline phase with a local structure similar to that of the amorphous phase. Cr nanoclusters were confirmed to exist in both the amorphous and crystalline phases. The presence of Cr nanoclusters induced Cr vacancies in the crystalline phase. These Cr vacancies generated hole carriers, leading to p-type conduction. Photoelectron spectroscopy of the Cr 2s core level clearly indicated a decrease in the fraction of Cr-Cr bonds and an increase in the fraction of Cr-Te bonds in crystalline CrGT upon annealing. Meanwhile, the coordination number of the Cr nanoclusters decreased as the number of Cr-Cr bonds was reduced. Together, these results imply that the origin of the increased resistance in crystalline CrGT is the filling of Cr vacancies by Cr atoms diffusing from Cr nanoclusters.

Original languageEnglish
Pages (from-to)43320-43329
Number of pages10
JournalACS Applied Materials and Interfaces
Volume11
Issue number46
DOIs
Publication statusPublished - 2019 Nov 20
Externally publishedYes

Keywords

  • Cr-Ge-Te
  • inverse resistance change
  • local structure
  • metastable phase
  • phase change material

ASJC Scopus subject areas

  • Materials Science(all)

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    Hatayama, S., Shuang, Y., Fons, P., Saito, Y., Kolobov, A. V., Kobayashi, K., Shindo, S., Ando, D., & Sutou, Y. (2019). Cr-Triggered Local Structural Change in Cr2Ge2Te6 Phase Change Material. ACS Applied Materials and Interfaces, 11(46), 43320-43329. https://doi.org/10.1021/acsami.9b11535