Crystal engineering approach toward Molecule-Based magnetic materials

Research output: Chapter in Book/Report/Conference proceedingChapter

1 Citation (Scopus)

Abstract

The crystal engineering approach Towardmolecule-Basedmagneticmaterials by controlling the molecular arrangement of the stable radical based on the directionality of the hydrogen bonding is described in connection with the magnetic and orbital interactions between the radical units. Several derivatives of 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl-3-oxide (NN) carrying a heterocycle having an NH proton donor site at the 2-position were designed. The imidazole derivative, Im-NN, formed a hydrogen-bonded chain, and close contact between the NO bonds of the NN group were observed between the chains. The benzimidazole and naphthoimidazole derivatives, BIm-NN and NIm-NN, formed a 1D assembled structure induced by intra- and intermolecular hydrogen bonds. Magnetic measurements revealed that a strong ferromagnetic interaction existed in BIm-NN, while dimeric and 1D chained antiferromagnetic interactions were observed in Im-NN and NIm-NN, respectively. The magneto-structural correlation of the 4- and 5-azaindole derivatives (4NIn-NN, 5NIn-NN) is also descried. In these crystals, the hydrogen bonds and -stacking have an important role in the crystal scaffolding, and the occurrence of a magnetic interaction is explained by contact of the SOMOs. These results indicate that the NHCC(NO)NO moiety is a useful synthon for propagating intermolecular magnetic interactions.

Original languageEnglish
Title of host publicationAdvances in Organic Crystal Chemistry: Comprehensive Reviews 2015
PublisherSpringer Japan
Pages669-688
Number of pages20
ISBN (Print)9784431555551, 9784431555544
DOIs
Publication statusPublished - 2015 Aug 6

Fingerprint

Crystal engineering
Magnetic materials
magnetic materials
engineering
Derivatives
Hydrogen bonds
Molecules
crystals
molecules
imidazoles
interactions
Crystals
hydrogen bonds
Magnetic variables measurement
Oxides
Protons
Hydrogen
hydrogen
magnetic measurement
occurrences

Keywords

  • Crystal engineering
  • Molecule-Based magnetism
  • Organic radical

ASJC Scopus subject areas

  • Chemistry(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Yoshioka, N. (2015). Crystal engineering approach toward Molecule-Based magnetic materials. In Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015 (pp. 669-688). Springer Japan. https://doi.org/10.1007/978-4-431-55555-1_34

Crystal engineering approach toward Molecule-Based magnetic materials. / Yoshioka, Naoki.

Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015. Springer Japan, 2015. p. 669-688.

Research output: Chapter in Book/Report/Conference proceedingChapter

Yoshioka, N 2015, Crystal engineering approach toward Molecule-Based magnetic materials. in Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015. Springer Japan, pp. 669-688. https://doi.org/10.1007/978-4-431-55555-1_34
Yoshioka N. Crystal engineering approach toward Molecule-Based magnetic materials. In Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015. Springer Japan. 2015. p. 669-688 https://doi.org/10.1007/978-4-431-55555-1_34
Yoshioka, Naoki. / Crystal engineering approach toward Molecule-Based magnetic materials. Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015. Springer Japan, 2015. pp. 669-688
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