TY - JOUR
T1 - Crystal Structure and Chromic Properties of an Iron(II) Complex Salt of a N-Salicylideneaniline Derivative
AU - Sugiyama, Haruki
AU - Uekusa, Hidehiro
N1 - Publisher Copyright:
© 2020 2020 © The Japan Society for Analytical Chemistry
PY - 2020
Y1 - 2020
N2 - The crystal structure of an iron(II) complex salt, [FeII(phen)3](SASO3–)2 (phen = phenanthroline; SASO3– = 3-{[(2-hydroxyphenyl)methylidene]amino}benzene-1-sulfonate)), was determined by single crystal X-ray structural analysis. It was revealed: monoclinic, C2/c, a = 26.951(3), b = 10.8492(8), c = 21.899(3)Å, β = 125.390(19)º, Z = 4, V = 5220.1(14)Å3R1 = 0.0493[I > 2σ(I)]. Although, 3-{[(2-hydroxyphenyl)methylidene]amino}benzene-1-sulfonic acid (SASO3H) was known as a photochromic compound, title compound did not exhibit photochromism due to the nonphotochromic molecular conformation of the SASO3– anions in the crystal.
AB - The crystal structure of an iron(II) complex salt, [FeII(phen)3](SASO3–)2 (phen = phenanthroline; SASO3– = 3-{[(2-hydroxyphenyl)methylidene]amino}benzene-1-sulfonate)), was determined by single crystal X-ray structural analysis. It was revealed: monoclinic, C2/c, a = 26.951(3), b = 10.8492(8), c = 21.899(3)Å, β = 125.390(19)º, Z = 4, V = 5220.1(14)Å3R1 = 0.0493[I > 2σ(I)]. Although, 3-{[(2-hydroxyphenyl)methylidene]amino}benzene-1-sulfonic acid (SASO3H) was known as a photochromic compound, title compound did not exhibit photochromism due to the nonphotochromic molecular conformation of the SASO3– anions in the crystal.
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U2 - 10.2116/xraystruct.36.31
DO - 10.2116/xraystruct.36.31
M3 - Article
AN - SCOPUS:85096982047
SN - 1883-3578
VL - 36
SP - 31
EP - 36
JO - X-ray Structure Analysis Online
JF - X-ray Structure Analysis Online
IS - 1
ER -