Crystal structure of 5,5′-dibromo-3,3′-di-tert-butyl-6,6′-dimethylbiphenyl-2,2′-diol

Rika Obata, Shigeru Ohba, Yasuaki Einaga, Shigeru Nishiyama, H. Stoeckli-Evans

Research output: Contribution to journalArticle

Abstract

The whole molecule of the title compound, C<inf>22</inf>H<inf>28</inf>Br<inf>2</inf>O<inf>2</inf>, is generated by twofold rotation symmetry. The dihedral angle of the biphenyl moiety is 85.05 (11)°. The hydroxy groups show intramolecular O - H⋯π interactions without any other hydrogen-bond acceptors. In the crystal, there are no other significant intermolecular interactions present.

Original languageEnglish
Pages (from-to)o278-o279
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number5
DOIs
Publication statusPublished - 2015 May 1

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Dihedral angle
Hydrogen bonds
Crystal structure
Crystals
crystal structure
Molecules
dihedral angle
interactions
hydrogen bonds
symmetry
crystals
molecules
diphenyl

Keywords

  • Axial chirality
  • Biphenyl
  • Crystal structure
  • O - H⋯π interactions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of 5,5′-dibromo-3,3′-di-tert-butyl-6,6′-dimethylbiphenyl-2,2′-diol. / Obata, Rika; Ohba, Shigeru; Einaga, Yasuaki; Nishiyama, Shigeru; Stoeckli-Evans, H.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 5, 01.05.2015, p. o278-o279.

Research output: Contribution to journalArticle

Obata, Rika ; Ohba, Shigeru ; Einaga, Yasuaki ; Nishiyama, Shigeru ; Stoeckli-Evans, H. / Crystal structure of 5,5′-dibromo-3,3′-di-tert-butyl-6,6′-dimethylbiphenyl-2,2′-diol. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 5. pp. o278-o279.
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