Crystal structure of bis(4-aminopyridine)bis(isothiocyanato)cobalt(II)

Haruki Sugiyama; Akiko Sekine; Hidehiro Uekusa

Crystal structure of bis(4-aminopyridine)bis(isothiocyanato)cobalt(II)

Haruki Sugiyama, Akiko Sekine, Hidehiro Uekusa

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Co(NCS)₂(C₅H₆N₂)₂], crystalized in the Pmmn space group; a = 13.029(5)Å, b = 14.551(6)Å, c = 4.1463(16)Å, V = 786.1(5)Å³, D_x = 1.535 g/cm³, and Z = 2. The R1 [I > 2σ(I)]; the wR₂ (all 978 independent reflections) values are 0.0570 and 0.1489, respectively. The Co complex has mm2 crystallographic symmetry, and also has a compressed tetrahedral coordination geometry. The complexes are stacked so as to form a characteristic one-dimensional chain structure; weak interactions exist between adjacent pyridine rings, and NCS and pyridine rings are observed.

Original language	English
Pages (from-to)	27-28
Number of pages	2
Journal	X-ray Structure Analysis Online
Volume	31
Issue number	4
Publication status	Published - 2015 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Materials Chemistry

Cite this

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title = "Crystal structure of bis(4-aminopyridine)bis(isothiocyanato)cobalt(II)",

abstract = "The title compound, [Co(NCS)2(C5H6N2)2], crystalized in the Pmmn space group; a = 13.029(5){\AA}, b = 14.551(6){\AA}, c = 4.1463(16){\AA}, V = 786.1(5){\AA}3, Dx = 1.535 g/cm3, and Z = 2. The R1 [I > 2σ(I)]; the wR2 (all 978 independent reflections) values are 0.0570 and 0.1489, respectively. The Co complex has mm2 crystallographic symmetry, and also has a compressed tetrahedral coordination geometry. The complexes are stacked so as to form a characteristic one-dimensional chain structure; weak interactions exist between adjacent pyridine rings, and NCS and pyridine rings are observed.",

author = "Haruki Sugiyama and Akiko Sekine and Hidehiro Uekusa",

year = "2015",

month = jan,

day = "1",

language = "English",

volume = "31",

pages = "27--28",

journal = "X-ray Structure Analysis Online",

issn = "1883-3578",

publisher = "Japan Society for Analytical Chemistry",

number = "4",

}

TY - JOUR

T1 - Crystal structure of bis(4-aminopyridine)bis(isothiocyanato)cobalt(II)

AU - Sugiyama, Haruki

AU - Sekine, Akiko

AU - Uekusa, Hidehiro

PY - 2015/1/1

Y1 - 2015/1/1

N2 - The title compound, [Co(NCS)2(C5H6N2)2], crystalized in the Pmmn space group; a = 13.029(5)Å, b = 14.551(6)Å, c = 4.1463(16)Å, V = 786.1(5)Å3, Dx = 1.535 g/cm3, and Z = 2. The R1 [I > 2σ(I)]; the wR2 (all 978 independent reflections) values are 0.0570 and 0.1489, respectively. The Co complex has mm2 crystallographic symmetry, and also has a compressed tetrahedral coordination geometry. The complexes are stacked so as to form a characteristic one-dimensional chain structure; weak interactions exist between adjacent pyridine rings, and NCS and pyridine rings are observed.

AB - The title compound, [Co(NCS)2(C5H6N2)2], crystalized in the Pmmn space group; a = 13.029(5)Å, b = 14.551(6)Å, c = 4.1463(16)Å, V = 786.1(5)Å3, Dx = 1.535 g/cm3, and Z = 2. The R1 [I > 2σ(I)]; the wR2 (all 978 independent reflections) values are 0.0570 and 0.1489, respectively. The Co complex has mm2 crystallographic symmetry, and also has a compressed tetrahedral coordination geometry. The complexes are stacked so as to form a characteristic one-dimensional chain structure; weak interactions exist between adjacent pyridine rings, and NCS and pyridine rings are observed.

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JO - X-ray Structure Analysis Online

JF - X-ray Structure Analysis Online

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ER -

Crystal structure of bis(4-aminopyridine)bis(isothiocyanato)cobalt(II)

Abstract

ASJC Scopus subject areas

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