Crystal structure of bis(4-aminopyridine)bis(isothiocyanato)cobalt(II)

Haruki Sugiyama, Akiko Sekine, Hidehiro Uekusa

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, [Co(NCS)2(C5H6N2)2], crystalized in the Pmmn space group; a = 13.029(5)Å, b = 14.551(6)Å, c = 4.1463(16)Å, V = 786.1(5)Å3, Dx = 1.535 g/cm3, and Z = 2. The R1 [I > 2σ(I)]; the wR2 (all 978 independent reflections) values are 0.0570 and 0.1489, respectively. The Co complex has mm2 crystallographic symmetry, and also has a compressed tetrahedral coordination geometry. The complexes are stacked so as to form a characteristic one-dimensional chain structure; weak interactions exist between adjacent pyridine rings, and NCS and pyridine rings are observed.

Original languageEnglish
Pages (from-to)27-28
Number of pages2
JournalX-ray Structure Analysis Online
Volume31
Issue number4
Publication statusPublished - 2015 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Materials Chemistry

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