Crystal structures of (S)-(+)-5-(3-bromo/chloro-4-isopropoxyphenyl)-5-methylimidazolidine-2,4-dione

Shigeru Ohba, Minoru Koura, Hisashi Sumidab, Kimiyuki Shibuya

Research output: Contribution to journalArticle

Abstract

In (S)-(+)-5-(3-bromo-4-isopropoxyphenyl)-5-methylimidazolidine-2,4-dione, C13H15BrN2O3, (I), the hydantoin groups are connected via intermolecular N-H. O hydrogen bonds, forming a terraced sheet structure. In the chloro analogue, (S)-(+)-5-(3-chloro-4-isopropoxyphenyl)-5-methylimidazolidine-2,4-dione, C13H15ClN2O3, (II), the intermolecular N-H. O hydrogen-bonding network forms a flat sheet. Comparison of the crystal structures reveals that (II) is more loosely packed than (I).

Original languageEnglish
Pages (from-to)184-187
Number of pages4
JournalActa Crystallographica Section E: Crystallographic Communications
Volume72
Issue number2
DOIs
Publication statusPublished - 2016 Feb 1

Keywords

  • absolute configuration
  • Crystal structure
  • hydantoin
  • hydrogen bonding

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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