Crystallization and sintering behavior of PZT prepared from metal alkoxides

Silvester Tursiloadi, Hiroaki Imai, Hiroshi Hirashima

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Powder precipitates and monolithic gels of lead zirconate-titanate (PZT) were prepared by hydrolysis of metal alkoxides in 1-propanol and acetylacetone/1-propanol solutions, respectively. The as-dried precipitates and gels were amorphous. Deposition of pyrochlore and perovskite at a relatively low temperature, 450°C, was observed for both the precipitate and gel. However, crystalline PbO was found in the gels heated at 300°C. The results showed that the homogeneity of the powder precipitate was better than that of the gel. After heating at 600°C, the diffraction peaks of only perovskite were found for both samples. Powder-compacts and gel compacts were sintered at temperatures higher than 900°C. The shrinkage of the gel-compacts after sintering was greater than that of the powder-compacts because of its small particle size.

Original languageEnglish
Pages (from-to)1069-1072
Number of pages4
JournalNippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
Volume103
Issue number1202
DOIs
Publication statusPublished - 1995 Jan 1

ASJC Scopus subject areas

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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