TY - JOUR
T1 - De Novo highly stereocontrolled synthesis of 2,6-dideoxy-C-3-branched carbohydrates by use of 2,6-anhydro-2-thio sugar
T2 - l-cladinose and its C-3 epimer
AU - Toshima, Kazunobu
AU - Yoshida, Takehito
AU - Mukaiyama, Satsuki
AU - Tatsuta, Kuniaki
PY - 1991/8/12
Y1 - 1991/8/12
N2 - L-Cladinose (1) and its C-3 epimer 2 were synthesized through a highly stereoselective addition of methyl anion to the C-3 carbonyl groups of α-anomer 9 and β-anomer 10 having 2,6-anhydro-2-thio structures, respectively, which were prepared from the common intermediate 6 in stereocontrolled fashion.
AB - L-Cladinose (1) and its C-3 epimer 2 were synthesized through a highly stereoselective addition of methyl anion to the C-3 carbonyl groups of α-anomer 9 and β-anomer 10 having 2,6-anhydro-2-thio structures, respectively, which were prepared from the common intermediate 6 in stereocontrolled fashion.
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U2 - 10.1016/S0040-4039(00)79886-8
DO - 10.1016/S0040-4039(00)79886-8
M3 - Article
AN - SCOPUS:0025734376
VL - 32
SP - 4139
EP - 4142
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 33
ER -