Abstract
[3]Cyclo-1,8-carbazolylene was found to undergo oxidative rearrangement by oxidation with 2,3-dichloro-5,6-dicyano-pbenzoquinone, giving a 9a-substituted carbazol-1-one derivative. This is the first example of a dearomative oxidative rearrangement of a carbazole or aniline derivative. The geometrical and electronic structures were elucidated by X-ray analysis, UV-vis absorption spectroscopy, and DFT calculations.
Original language | English |
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Pages (from-to) | 1357-1359 |
Number of pages | 3 |
Journal | Chemistry Letters |
Volume | 47 |
Issue number | 11 |
DOIs | |
Publication status | Published - 2018 |
Keywords
- Carbazole
- Oxidation
- Rearrangement
ASJC Scopus subject areas
- Chemistry(all)