Abstract
[3]Cyclo-1,8-carbazolylene was found to undergo oxidative rearrangement by oxidation with 2,3-dichloro-5,6-dicyano-pbenzoquinone, giving a 9a-substituted carbazol-1-one derivative. This is the first example of a dearomative oxidative rearrangement of a carbazole or aniline derivative. The geometrical and electronic structures were elucidated by X-ray analysis, UV-vis absorption spectroscopy, and DFT calculations.
| Original language | English |
|---|---|
| Pages (from-to) | 1357-1359 |
| Number of pages | 3 |
| Journal | Chemistry Letters |
| Volume | 47 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2018 Jan 1 |
Keywords
- Carbazole
- Oxidation
- Rearrangement
ASJC Scopus subject areas
- Chemistry(all)
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Cite this
Yasui, M., Ohtsu, H., Kawano, M., Hanaya, K., Sugai, T., & Higashibayashi, S. (2018). Dearomative Oxidative Rearrangement of [3]Cyclo-1,8-carbazolylene. Chemistry Letters, 47(11), 1357-1359. https://doi.org/10.1246/cl.180637