Decarboxylation-triggered homo-Nazarov cyclization of cyclic enol carbonates catalyzed by rhenium complex

Natsuki Kimaru, Keiichi Komatsuki, Kodai Saito, Tohru Yamada

Research output: Contribution to journalArticlepeer-review

Abstract

Decarboxylative homo-Nazarov cyclization catalyzed by a Lewis acid was achieved using a cyclic enol carbonate bearing a cyclopropane moiety as a substrate. Various substrates were converted into the corresponding multi-substituted cyclohexenones in good yieldsviadecarboxylation, followed by 6-membered ring formation involving cyclopropane-ring-opening.

Original languageEnglish
Pages (from-to)6133-6136
Number of pages4
JournalChemical Communications
Volume57
Issue number50
DOIs
Publication statusPublished - 2021 Jun 25

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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