Dehydrogenative silylation of 1,5-dienes with hydrosilanes catalyzed by RhCl(PPh3)3

Fumitoshi Kakiuchi, Katsuo Nogami, Naoto Chatani, Yoshio Seki, Shinji Murai

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh3)3 as a catalyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silylation instead of the usual hydrosilylation products.

Original languageEnglish
Pages (from-to)4748-4750
Number of pages3
JournalOrganometallics
Volume12
Issue number12
Publication statusPublished - 1993
Externally publishedYes

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Hydrosilylation
dienes
Catalysts
catalysts
products
chlorotris(triphenylphosphine)rhodium

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Kakiuchi, F., Nogami, K., Chatani, N., Seki, Y., & Murai, S. (1993). Dehydrogenative silylation of 1,5-dienes with hydrosilanes catalyzed by RhCl(PPh3)3. Organometallics, 12(12), 4748-4750.

Dehydrogenative silylation of 1,5-dienes with hydrosilanes catalyzed by RhCl(PPh3)3. / Kakiuchi, Fumitoshi; Nogami, Katsuo; Chatani, Naoto; Seki, Yoshio; Murai, Shinji.

In: Organometallics, Vol. 12, No. 12, 1993, p. 4748-4750.

Research output: Contribution to journalArticle

Kakiuchi, F, Nogami, K, Chatani, N, Seki, Y & Murai, S 1993, 'Dehydrogenative silylation of 1,5-dienes with hydrosilanes catalyzed by RhCl(PPh3)3', Organometallics, vol. 12, no. 12, pp. 4748-4750.
Kakiuchi, Fumitoshi ; Nogami, Katsuo ; Chatani, Naoto ; Seki, Yoshio ; Murai, Shinji. / Dehydrogenative silylation of 1,5-dienes with hydrosilanes catalyzed by RhCl(PPh3)3. In: Organometallics. 1993 ; Vol. 12, No. 12. pp. 4748-4750.
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