Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh3)3

Fumitoshi Kakiuchi, Katsuo Nogami, Naoto Chatani, Yoshio Seki, Shinji Murai

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh3)3 as a catalyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silylation instead of the usual hydrosilylation products.

Original languageEnglish
Pages (from-to)4748-4750
Number of pages3
JournalOrganometallics
Volume12
Issue number12
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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