Abstract
Novel chiral hybrid ligands containing an unsymmetrical spiro[4.5]decane skeleton with isoxazole and isoxazoline as the two coordinating units have been synthesized. Pd complexes of these ligands were found to be effective in activating olefins towards enantioselective tandem cyclization of a dialkenyl alcohol, providing the cyclized products in up to 97% ee.
Original language | English |
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Pages (from-to) | 919-923 |
Number of pages | 5 |
Journal | Tetrahedron Asymmetry |
Volume | 18 |
Issue number | 8 |
DOIs | |
Publication status | Published - 2007 May 16 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry