Determination of the field strengths of weak neutral ligands having oxygen as coordination atom

Akito Hoshino, Mikio Nakamura

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Abstract

Weakness of various neutral ligands having oxygen as coordination atom was ranked on the basis of the pyrrole proton chemical shifts of planar [Fe(TPP)L2]+. Furthermore, weakness of the ligands, which is difficult to determine from the NMR data of planar [Fe(TPP)L 2]+, was successfully differentiated by the use of highly ruffled [Fe(TiPrP)L2]+. Among the 10 ligands examined, THF turned out to be the weakest ligand.

Original languageEnglish
Article numberCL-040613
Pages (from-to)1234-1235
Number of pages2
JournalChemistry Letters
Volume33
Issue number10
DOIs
Publication statusPublished - 2004 Oct 5

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ASJC Scopus subject areas

  • Chemistry(all)

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