Determination of the field strengths of weak neutral ligands having oxygen as coordination atom

Akito Hoshino, Mikio Nakamura

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Weakness of various neutral ligands having oxygen as coordination atom was ranked on the basis of the pyrrole proton chemical shifts of planar [Fe(TPP)L2]+. Furthermore, weakness of the ligands, which is difficult to determine from the NMR data of planar [Fe(TPP)L 2]+, was successfully differentiated by the use of highly ruffled [Fe(TiPrP)L2]+. Among the 10 ligands examined, THF turned out to be the weakest ligand.

Original languageEnglish
Article numberCL-040613
Pages (from-to)1234-1235
Number of pages2
JournalChemistry Letters
Volume33
Issue number10
DOIs
Publication statusPublished - 2004 Oct 5

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Oxygen
Ligands
Atoms
Pyrroles
Chemical shift
Protons
Nuclear magnetic resonance

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Determination of the field strengths of weak neutral ligands having oxygen as coordination atom. / Hoshino, Akito; Nakamura, Mikio.

In: Chemistry Letters, Vol. 33, No. 10, CL-040613, 05.10.2004, p. 1234-1235.

Research output: Contribution to journalArticle

Hoshino, Akito ; Nakamura, Mikio. / Determination of the field strengths of weak neutral ligands having oxygen as coordination atom. In: Chemistry Letters. 2004 ; Vol. 33, No. 10. pp. 1234-1235.
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