Determination of the 13C NMR chemical shifts in an a 2u type iron(III) porphyrin cation radical

Akito Hoshino, Mikio Nakamura

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The 13C NMR chemical shifts of all the carbons in an a 2u type iron(III) porphyrin radical cation, [Fe(TPP)Cl]+, have been determined for the first time by the titration method as well as by the chemical shift correlation; they are 2230, 1050, and -1910 ppm for the α-pyrrole, β-pyrrole, and meso carbon atoms, respectively.

Original languageEnglish
Pages (from-to)915-917
Number of pages3
JournalChemical Communications
Issue number7
DOIs
Publication statusPublished - 2005 Feb 21

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Pyrroles
Porphyrins
Chemical shift
Cations
Carbon
Iron
Positive ions
Nuclear magnetic resonance
Titration
Atoms

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Determination of the 13C NMR chemical shifts in an a 2u type iron(III) porphyrin cation radical. / Hoshino, Akito; Nakamura, Mikio.

In: Chemical Communications, No. 7, 21.02.2005, p. 915-917.

Research output: Contribution to journalArticle

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