Determination of the 13C NMR chemical shifts in an a 2u type iron(III) porphyrin cation radical

Akito Hoshino, Mikio Nakamura

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The 13C NMR chemical shifts of all the carbons in an a 2u type iron(III) porphyrin radical cation, [Fe(TPP)Cl]+, have been determined for the first time by the titration method as well as by the chemical shift correlation; they are 2230, 1050, and -1910 ppm for the α-pyrrole, β-pyrrole, and meso carbon atoms, respectively.

Original languageEnglish
Pages (from-to)915-917
Number of pages3
JournalChemical Communications
Issue number7
DOIs
Publication statusPublished - 2005 Feb 21

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Determination of the <sup>13</sup>C NMR chemical shifts in an a <sub>2u</sub> type iron(III) porphyrin cation radical'. Together they form a unique fingerprint.

  • Cite this