Abstract
The disproportionation of triethoxysilane was carried out in a fixed-bed flow reactor over the solids obtained by heat-treating calcium hydroxide at various temperatures. In the disproportionation, the reaction proceeding to completeness to afford silane and tetraethoxysilane occurs to far lesser extent: predominantly diethoxysilane is obtained together with tetraethoxysilane. Dimethoxysilane is obtained by the disproportionation of trimethoxysilane also over the heat-treated calcium hydroxide.
| Original language | English |
|---|---|
| Pages (from-to) | 75-78 |
| Number of pages | 4 |
| Journal | Catalysis Letters |
| Volume | 48 |
| Issue number | 1-2 |
| Publication status | Published - 1997 Dec 1 |
| Externally published | Yes |
Keywords
- Calcium hydroxide
- Diethoxysilane
- Dimethoxysilane
- Disproportionation
- Triethoxysilane
- Trimethoxysilane
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)