Dimeric copper(II) 3,3-dimethylbutyrate adducts with ethanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid

Masato Goto, Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii

Research output: Contribution to journalArticle

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Abstract

In the crystals of the five title compounds, tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(ethanol-O)dicopper(II)- ethanol (1/2), [Cu2(C6H11O2)4(C 2H6O)2]·2C2H6O, (I), tetrakis(μ-3,3-dimethylbutyrato-O:O′)bis(2-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (II), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (III), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(4-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (IV), and tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3,3-dimethylbutyric acid-O)dicopper(II), [Cu2(C6H11O2)4(C 6H12O2)2], (V), the dinuclear CuII complexes all have centrosymmetric cage structures and (IV) has two independent molecules. The Cu⋯Cu separations are: (I) 2.602 (3) Å, (II) 2.666 (3) Å, (III) 2.640 (2) Å, (IV) 2.638 (4) Å and (V) 2.599 (1) Å.

Original languageEnglish
Pages (from-to)7-11
Number of pages5
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number1
Publication statusPublished - 2000 Jan

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adducts
Copper
ethyl alcohol
Ethanol
copper
acids
Acids
Crystals
Molecules
crystals
molecules
4-methylpyridine
3-methylpyridine
2-picoline

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

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Dimeric copper(II) 3,3-dimethylbutyrate adducts with ethanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid. / Goto, Masato; Kani, Yoshiyuki; Tsuchimoto, Masanobu; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 1, 01.2000, p. 7-11.

Research output: Contribution to journalArticle

Goto, Masato ; Kani, Yoshiyuki ; Tsuchimoto, Masanobu ; Ohba, Shigeru ; Matsushima, Hideaki ; Tokii, Tadashi. / Dimeric copper(II) 3,3-dimethylbutyrate adducts with ethanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid. In: Acta Crystallographica Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 1. pp. 7-11.
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title = "Dimeric copper(II) 3,3-dimethylbutyrate adducts with ethanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid",
abstract = "In the crystals of the five title compounds, tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(ethanol-O)dicopper(II)- ethanol (1/2), [Cu2(C6H11O2)4(C 2H6O)2]·2C2H6O, (I), tetrakis(μ-3,3-dimethylbutyrato-O:O′)bis(2-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (II), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (III), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(4-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (IV), and tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3,3-dimethylbutyric acid-O)dicopper(II), [Cu2(C6H11O2)4(C 6H12O2)2], (V), the dinuclear CuII complexes all have centrosymmetric cage structures and (IV) has two independent molecules. The Cu⋯Cu separations are: (I) 2.602 (3) {\AA}, (II) 2.666 (3) {\AA}, (III) 2.640 (2) {\AA}, (IV) 2.638 (4) {\AA} and (V) 2.599 (1) {\AA}.",
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T1 - Dimeric copper(II) 3,3-dimethylbutyrate adducts with ethanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid

AU - Goto, Masato

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Tokii, Tadashi

PY - 2000/1

Y1 - 2000/1

N2 - In the crystals of the five title compounds, tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(ethanol-O)dicopper(II)- ethanol (1/2), [Cu2(C6H11O2)4(C 2H6O)2]·2C2H6O, (I), tetrakis(μ-3,3-dimethylbutyrato-O:O′)bis(2-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (II), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (III), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(4-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (IV), and tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3,3-dimethylbutyric acid-O)dicopper(II), [Cu2(C6H11O2)4(C 6H12O2)2], (V), the dinuclear CuII complexes all have centrosymmetric cage structures and (IV) has two independent molecules. The Cu⋯Cu separations are: (I) 2.602 (3) Å, (II) 2.666 (3) Å, (III) 2.640 (2) Å, (IV) 2.638 (4) Å and (V) 2.599 (1) Å.

AB - In the crystals of the five title compounds, tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(ethanol-O)dicopper(II)- ethanol (1/2), [Cu2(C6H11O2)4(C 2H6O)2]·2C2H6O, (I), tetrakis(μ-3,3-dimethylbutyrato-O:O′)bis(2-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (II), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (III), tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(4-methylpyridine-N) dicopper(II), [Cu2(C6H11O2)4(C 6H7N)2], (IV), and tetrakis-(μ-3,3-dimethylbutyrato-O:O′)bis(3,3-dimethylbutyric acid-O)dicopper(II), [Cu2(C6H11O2)4(C 6H12O2)2], (V), the dinuclear CuII complexes all have centrosymmetric cage structures and (IV) has two independent molecules. The Cu⋯Cu separations are: (I) 2.602 (3) Å, (II) 2.666 (3) Å, (III) 2.640 (2) Å, (IV) 2.638 (4) Å and (V) 2.599 (1) Å.

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