Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate

Hiroo Nakagawa, Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.

Original languageEnglish
Pages (from-to)12-16
Number of pages5
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number1
Publication statusPublished - 2000 Jan

Fingerprint

quinoline
adducts
Copper
pyridines
copper
Crystals
crystals
pyridine
3-methylpyridine
2-picoline

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate. / Nakagawa, Hiroo; Kani, Yoshiyuki; Tsuchimoto, Masanobu; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 1, 01.2000, p. 12-16.

Research output: Contribution to journalArticle

Nakagawa, Hiroo ; Kani, Yoshiyuki ; Tsuchimoto, Masanobu ; Ohba, Shigeru ; Matsushima, Hideaki ; Tokii, Tadashi. / Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate. In: Acta Crystallographica Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 1. pp. 12-16.
@article{872503cf3a6847589e877477f99cebc6,
title = "Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate",
abstract = "In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) {\AA}. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) {\AA}, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.",
author = "Hiroo Nakagawa and Yoshiyuki Kani and Masanobu Tsuchimoto and Shigeru Ohba and Hideaki Matsushima and Tadashi Tokii",
year = "2000",
month = "1",
language = "English",
volume = "56",
pages = "12--16",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "1",

}

TY - JOUR

T1 - Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate

AU - Nakagawa, Hiroo

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Tokii, Tadashi

PY - 2000/1

Y1 - 2000/1

N2 - In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.

AB - In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.

UR - http://www.scopus.com/inward/record.url?scp=0006929510&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0006929510&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0006929510

VL - 56

SP - 12

EP - 16

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 1

ER -