Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate

Hiroo Nakagawa; Yoshiyuki Kani; Masanobu Tsuchimoto; Shigeru Ohba; Hideaki Matsushima; Tadashi Tokii

doi:10.1107/S0108270199012147

Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate

Hiroo Nakagawa, Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu₂(C₅H₁₁O₂Si)₄(C ₅H₅N)₂], (I), the dinuclear Cu^II complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu₂(C₅H₁₁O₂Si)₄(C ₆H₇N)₂], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu₂(C₅H₁₁O₂Si)₄(C ₆H₇N)₂], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu₂(C₅H₁₁O₂Si)₄-(C ₉H₇N)₂], (IV), the centrosymmetric dinuclear Cu^II complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu₂(C₅H₁₁O₂Si)₄] _n, (V), the dinuclear Cu^II units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.

Original language	English
Pages (from-to)	12-16
Number of pages	5
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	1
DOIs	https://doi.org/10.1107/S0108270199012147
Publication status	Published - 2000 Jan

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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Nakagawa, H., Kani, Y., Tsuchimoto, M., Ohba, S., Matsushima, H., & Tokii, T. (2000). Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate. Acta Crystallographica Section C: Crystal Structure Communications, 56(1), 12-16. https://doi.org/10.1107/S0108270199012147

Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate. / Nakagawa, Hiroo; Kani, Yoshiyuki; Tsuchimoto, Masanobu; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 1, 01.2000, p. 12-16.

Research output: Contribution to journal › Article

Nakagawa, H, Kani, Y, Tsuchimoto, M, Ohba, S, Matsushima, H & Tokii, T 2000, 'Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate', Acta Crystallographica Section C: Crystal Structure Communications, vol. 56, no. 1, pp. 12-16. https://doi.org/10.1107/S0108270199012147

Nakagawa, Hiroo ; Kani, Yoshiyuki ; Tsuchimoto, Masanobu ; Ohba, Shigeru ; Matsushima, Hideaki ; Tokii, Tadashi. / Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate. In: Acta Crystallographica Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 1. pp. 12-16.

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title = "Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate",

abstract = "In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) {\AA}. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) {\AA}, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.",

author = "Hiroo Nakagawa and Yoshiyuki Kani and Masanobu Tsuchimoto and Shigeru Ohba and Hideaki Matsushima and Tadashi Tokii",

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T1 - Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate

AU - Nakagawa, Hiroo

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Tokii, Tadashi

PY - 2000/1

Y1 - 2000/1

N2 - In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.

AB - In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.

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