Abstract
In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.
| Original language | English |
|---|---|
| Pages (from-to) | 12-16 |
| Number of pages | 5 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 56 |
| Issue number | 1 |
| Publication status | Published - 2000 Jan |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Structural Biology
Cite this
Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate. / Nakagawa, Hiroo; Kani, Yoshiyuki; Tsuchimoto, Masanobu; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 1, 01.2000, p. 12-16.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine and quinoline, and a polymeric copper(II) trimethylsilylacetate
AU - Nakagawa, Hiroo
AU - Kani, Yoshiyuki
AU - Tsuchimoto, Masanobu
AU - Ohba, Shigeru
AU - Matsushima, Hideaki
AU - Tokii, Tadashi
PY - 2000/1
Y1 - 2000/1
N2 - In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.
AB - In the crystals of bis(pyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4(C 5H5N)2], (I), the dinuclear CuII complexes have cage structures with Cu⋯Cu distances of 2.632 (1) and 2.635 (1) Å. In the crystals of bis-(2-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (II), bis(3-methylpyridine-N)tetrakis(μ-trimethylsilylacetato-O:O′) dicopper(II), [Cu2(C5H11O2Si)4(C 6H7N)2], (III), and bis(quinoline-N)-(μ-trimethylsilylacetato-O:O′)dicopper(II), [Cu2(C5H11O2Si)4-(C 9H7N)2], (IV), the centrosymmetric dinuclear CuII complexes have a cage structure with Cu⋯Cu distances of 2.664 (1), 2.638 (3) and 2.665 (1) Å, respectively. In the crystals of catena-poly[tetrakis(μ-trimethylsilylacetato-O:O′)-dicopper(II)], [Cu2(C5H11O2Si)4] n, (V), the dinuclear CuII units of a cage structure are linked by the cyclic Cu-O bonds at the apical positions to form a linear chain by use of a glide translation.
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M3 - Article
AN - SCOPUS:0006929510
VL - 56
SP - 12
EP - 16
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 1
ER -