Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

Shunsuke Onodera; Soya Ishikawa; Takuya Kochi; Fumitoshi Kakiuchi

doi:10.1021/jacs.8b03718

Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

Shunsuke Onodera, Soya Ishikawa, Takuya Kochi, Fumitoshi Kakiuchi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

A novel method for direct transformation of allyl groups in allylbenzene derivatives to alkenyl groups via rhodium-catalyzed C-C bond cleavage is reported. The alkenylation with styrenes of allylbenzenes containing pyridyl and pyrazolyl groups as a directing group proceeded efficiently to give alkenylation products. We also developed a new protocol for transformation of an ortho-prenylated phenol to an aniline derivative.

Original language	English
Pages (from-to)	9788-9792
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	31
DOIs	https://doi.org/10.1021/jacs.8b03718
Publication status	Published - 2018 Aug 8

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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AU - Kakiuchi, Fumitoshi

PY - 2018/8/8

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Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

Abstract

ASJC Scopus subject areas

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