A novel method for direct transformation of allyl groups in allylbenzene derivatives to alkenyl groups via rhodium-catalyzed C-C bond cleavage is reported. The alkenylation with styrenes of allylbenzenes containing pyridyl and pyrazolyl groups as a directing group proceeded efficiently to give alkenylation products. We also developed a new protocol for transformation of an ortho-prenylated phenol to an aniline derivative.
|Number of pages||5|
|Journal||Journal of the American Chemical Society|
|Publication status||Published - 2018 Aug 8|
ASJC Scopus subject areas
- Colloid and Surface Chemistry