Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

Shunsuke Onodera, Soya Ishikawa, Takuya Kochi, Fumitoshi Kakiuchi

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A novel method for direct transformation of allyl groups in allylbenzene derivatives to alkenyl groups via rhodium-catalyzed C-C bond cleavage is reported. The alkenylation with styrenes of allylbenzenes containing pyridyl and pyrazolyl groups as a directing group proceeded efficiently to give alkenylation products. We also developed a new protocol for transformation of an ortho-prenylated phenol to an aniline derivative.

Original languageEnglish
JournalJournal of the American Chemical Society
DOIs
Publication statusAccepted/In press - 2018 Apr 6

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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