Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines

Yuji Kawato; Naoya Kumagai; Masakatsu Shibasaki

doi:10.1039/c3cc47117a

Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines

Yuji Kawato, Naoya Kumagai, Masakatsu Shibasaki

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Direct catalytic addition of acetonitrile pronucleophiles to thiophosphinoylimines is described. Soft Lewis acid-hard Brønsted base cooperative catalysis is crucial to promote this elusive carbon-carbon bond-forming reaction in an enantioselective fashion.

Original language	English
Pages (from-to)	11227-11229
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	95
DOIs	https://doi.org/10.1039/c3cc47117a
Publication status	Published - 2013 Nov 5
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc47117a

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title = "Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines",

abstract = "Direct catalytic addition of acetonitrile pronucleophiles to thiophosphinoylimines is described. Soft Lewis acid-hard Br{\o}nsted base cooperative catalysis is crucial to promote this elusive carbon-carbon bond-forming reaction in an enantioselective fashion.",

author = "Yuji Kawato and Naoya Kumagai and Masakatsu Shibasaki",

year = "2013",

month = nov,

day = "5",

doi = "10.1039/c3cc47117a",

language = "English",

volume = "49",

pages = "11227--11229",

journal = "Chemical Communications",

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T1 - Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines

AU - Kawato, Yuji

AU - Kumagai, Naoya

AU - Shibasaki, Masakatsu

PY - 2013/11/5

Y1 - 2013/11/5

N2 - Direct catalytic addition of acetonitrile pronucleophiles to thiophosphinoylimines is described. Soft Lewis acid-hard Brønsted base cooperative catalysis is crucial to promote this elusive carbon-carbon bond-forming reaction in an enantioselective fashion.

AB - Direct catalytic addition of acetonitrile pronucleophiles to thiophosphinoylimines is described. Soft Lewis acid-hard Brønsted base cooperative catalysis is crucial to promote this elusive carbon-carbon bond-forming reaction in an enantioselective fashion.

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U2 - 10.1039/c3cc47117a

DO - 10.1039/c3cc47117a

M3 - Article

C2 - 24158566

AN - SCOPUS:84887101745

SN - 1359-7345

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SP - 11227

EP - 11229

JO - Chemical Communications

JF - Chemical Communications

IS - 95

ER -

Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines

Abstract

ASJC Scopus subject areas

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