Direct catalytic asymmetric michael reaction of α-hydroxyketone promoted by Et2Zn/linkedbinol complex

Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai

Research output: Chapter in Book/Report/Conference proceedingChapter

1 Citation (Scopus)

Abstract

This chapter contains sections titled: Direct catalytic asymmetric aldol reaction of a a-hydroxyketone promoted by an Et2Zn/linked-BINOL complex Highly enantioselective direct aldol reaction catalysed by a novel small organic molecule Direct catalytic asymmetric Michael reaction of a-hydroxyketone promoted by Et2Zn/linked-BINOL complex Catalytic enantioselective Michael reaction catalysed by well-defined chiral ruthenium-amido complexes.

Original languageEnglish
Title of host publicationCatalysts for Fine Chemical Synthesis
Subtitle of host publicationMetal Catalysed Carbon-Carbon Bond-Forming Reactions
Publisherwiley
Pages210-216
Number of pages7
Volume3
ISBN (Electronic)9780470862018
ISBN (Print)9780470861998
DOIs
Publication statusPublished - 2005 Jan 1
Externally publishedYes

Keywords

  • Asymmetric carbon-carbon bond formation
  • Catalytic asymmetric aldol reaction
  • Catalytic asymmetric michael reaction
  • Chiral rutheniumamido complex
  • Direct aldol reaction
  • High atom economy
  • L-proline amide moiety
  • Terminal hydroxyl group

ASJC Scopus subject areas

  • Chemistry(all)

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