Direct observation of conformers caused by the difference in ligand orientation in low spin iron(III) porphyrin complex

Takahisa Ikeue, Tatsuya Yamaguchi, Yoshiki Ohgo, Mikio Nakamura

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

EPR spectrum of low spin bis(dimethylaminopyridine)(3,8, 13,18-tetramesityl-2,7,12,17-tetramethylporphyrinato)iron(III) perchlorate taken in frozen CH2Cl2 solution at 4.2 K showed both large gmax and rhombic type signals. The result has been explained in terms of the presence of two conformers where the dihedral angles between two ligands are different.

Original languageEnglish
Pages (from-to)342-343
Number of pages2
JournalChemistry Letters
Issue number4
DOIs
Publication statusPublished - 2000 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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