Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

Masaki Okamoto, Satoshi Onodera, Yuji Yamamoto, Eiichi Suzuki, Yoshio Ono

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.

Original languageEnglish
Pages (from-to)1275-1276
Number of pages2
JournalChemical Communications
Issue number12
DOIs
Publication statusPublished - 1998 Jun 21
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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