Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Masaki Okamoto, Takuya Asano, Eiichi Suzuki

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

Original languageEnglish
Pages (from-to)33-36
Number of pages4
JournalCatalysis Letters
Volume78
Issue number1-4
DOIs
Publication statusPublished - 2002 Mar 1
Externally publishedYes

Fingerprint

Germanium
Chlorides
Metals
Catalysts
Ions
Copper
chlorobenzene
cuprous chloride
germanium chloride

Keywords

  • Copper catalyst
  • Direct synthesis
  • Metallic germanium
  • Phenylchlorogermane
  • Silver catalyst

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts. / Okamoto, Masaki; Asano, Takuya; Suzuki, Eiichi.

In: Catalysis Letters, Vol. 78, No. 1-4, 01.03.2002, p. 33-36.

Research output: Contribution to journalArticle

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