Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Masaki Okamoto; Takuya Asano; Eiichi Suzuki

doi:10.1023/A:1014992915564

Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Masaki Okamoto, Takuya Asano, Eiichi Suzuki

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

Original language	English
Pages (from-to)	33-36
Number of pages	4
Journal	Catalysis Letters
Volume	78
Issue number	1-4
DOIs	https://doi.org/10.1023/A:1014992915564
Publication status	Published - 2002 Mar
Externally published	Yes

Keywords

Copper catalyst
Direct synthesis
Metallic germanium
Phenylchlorogermane
Silver catalyst

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1023/A:1014992915564

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title = "Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts",

abstract = "In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.",

keywords = "Copper catalyst, Direct synthesis, Metallic germanium, Phenylchlorogermane, Silver catalyst",

author = "Masaki Okamoto and Takuya Asano and Eiichi Suzuki",

year = "2002",

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doi = "10.1023/A:1014992915564",

language = "English",

volume = "78",

pages = "33--36",

journal = "Catalysis Letters",

issn = "1011-372X",

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T1 - Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

AU - Okamoto, Masaki

AU - Asano, Takuya

AU - Suzuki, Eiichi

PY - 2002/3

Y1 - 2002/3

N2 - In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

AB - In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

KW - Copper catalyst

KW - Direct synthesis

KW - Metallic germanium

KW - Phenylchlorogermane

KW - Silver catalyst

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JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-4

ER -

Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Abstract

Keywords

ASJC Scopus subject areas

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