Abstract
Ruthenium-catalyzed addition of 3′-methyl-, 3′-trifluoromethyl-, and 3′-N,N-dimethylaminoacetophenones to an olefin proceeds site selectively at 6′ CH bonds to give the 1:1 CH/olefin addition products in high yields. In contrast, the addition of 3′-methoxyacetophenone takes place preferentially at the CH bond at the more congested 2′ position.
| Original language | English |
|---|---|
| Pages (from-to) | 151-152 |
| Number of pages | 2 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 504 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1995 Nov 29 |
| Externally published | Yes |
Keywords
- Acetophenone
- Carbon-hydrogen bond cleavage
- Catalysis
- Catalytic CH/olefin coupling
- Ketone
- Ruthenium
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry