Disorder of Hydrofluorocarbon Molecules Entrapped in the Water Cages of Structure i Clathrate Hydrate

Satoshi Takeya, Konstantin A. Udachin, Igor L. Moudrakovski, Ryo Ohmura, John A. Ripmeester

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Water versus fluorine: Clathrate hydrates encaging hydrofluorocarbons as guests show both isotropic and anisotropic distributions within host water cages, depending on the number of fluorine atoms in the guest molecule; this is caused by changes in intermolecular interactions to host water molecules in the hydrates (see figure).

Original languageEnglish
Pages (from-to)7567-7573
Number of pages7
JournalChemistry - A European Journal
Volume22
Issue number22
DOIs
Publication statusPublished - 2016 May 23

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Hydrates
Fluorine
Molecules
Water
Atoms

Keywords

  • clathrates
  • fluorine
  • host-guest systems
  • hydrates
  • X-ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Disorder of Hydrofluorocarbon Molecules Entrapped in the Water Cages of Structure i Clathrate Hydrate. / Takeya, Satoshi; Udachin, Konstantin A.; Moudrakovski, Igor L.; Ohmura, Ryo; Ripmeester, John A.

In: Chemistry - A European Journal, Vol. 22, No. 22, 23.05.2016, p. 7567-7573.

Research output: Contribution to journalArticle

Takeya, Satoshi ; Udachin, Konstantin A. ; Moudrakovski, Igor L. ; Ohmura, Ryo ; Ripmeester, John A. / Disorder of Hydrofluorocarbon Molecules Entrapped in the Water Cages of Structure i Clathrate Hydrate. In: Chemistry - A European Journal. 2016 ; Vol. 22, No. 22. pp. 7567-7573.
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