Disproportionation of triethoxysilane over KF/Al2O3 and heat-treated hydrotalcite

Eiichi Suzuki, Youichi Nomoto, Masaki Okamoto, Yoshio Ono

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13 Citations (Scopus)

Abstract

Under fixed-bed flow conditions, silane, diethoxysilane, and tetraethoxysilane are formed by the disproportionation of triethoxysilane over a KF/Al2O3 or a heat-treated hydrotalcite catalyst. The reactions at 393 K give preponderantly either silane with 17-21% yields or diethoxysilane with 5-10% yields. The preponderance depends on the contact time and the amount of KF loaded on Al2O3.

Original languageEnglish
Pages (from-to)7-10
Number of pages4
JournalApplied Catalysis A: General
Volume167
Issue number1
DOIs
Publication statusPublished - 1998 Feb 5

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Keywords

  • Alkoxysilane
  • Disproportionation
  • Hydrotalcite
  • KF/AlO
  • Silane

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

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