Effect of preliminary mechanical treatment on the microhomogenization during heating of hydrous gels as precursors for lead titanate

Satoru Komatsubara, Tetsuhiko Isobe, Mamoru Senna

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Change in compositional microhomogeneity as a function of temperature was determined for various hydrous gels obtained from a component sol mixture as precursors for PbTiO3. The local molar ratio, Pb:Ti, was determined by energy dispersive spectroscopy with a 25-nm electron beam. Homogenization during heating was accelerated by preliminary ball milling or pressing of the sol mixture. The mechanism of homogenization is discussed in the present paper with respect to mechanochemical effects.

Original languageEnglish
Pages (from-to)278-282
Number of pages5
JournalJournal of the American Ceramic Society
Volume77
Issue number1
Publication statusPublished - 1994 Jan

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Polymethyl Methacrylate
Sols
Gels
Lead
Heating
Ball milling
Energy dispersive spectroscopy
Electron beams
Temperature
lead titanate

ASJC Scopus subject areas

  • Ceramics and Composites

Cite this

Effect of preliminary mechanical treatment on the microhomogenization during heating of hydrous gels as precursors for lead titanate. / Komatsubara, Satoru; Isobe, Tetsuhiko; Senna, Mamoru.

In: Journal of the American Ceramic Society, Vol. 77, No. 1, 01.1994, p. 278-282.

Research output: Contribution to journalArticle

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