Effects of a nonplanar porphyrin rings on the spin-spin interactions in low-spin ferric porphyrin radical cations

Takahisa Ikeue, Yoshiki Ohgo, Mikio Nakamura

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Low-spin ferric porphyrin radical cations formed by the oxidation of chloro(meso-tetraalkylporphyrinato)iron(III) followed by the addition of bulky 2-methylimidazole show antiferromagnetic coupling, which is interpreted in terms of the interaction between porphyrin a2u and iron dxy orbitals caused by the S4 ruffling of the porphyrin core.

Original languageEnglish
Pages (from-to)220-221
Number of pages2
JournalChemical Communications
Issue number2
DOIs
Publication statusPublished - 2003

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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